Issue 17, 2022
From the journal:

Organic Chemistry Frontiers

Synthesis of 1,4-diketones via palladium/photo-cocatalyzed dehydrogenative cross-coupling†

Pei Fan,ab   Yujia Maob  and  Chuan Wang ORCID logo *b  

* Corresponding authors

a School of Chemistry and Materials Engineering, Anhui Province Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, Anhui 232038, P. R. China

b Department of Chemistry, Center for Excellence in Molecular Synthesis of CAS, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: chuanw@ustc.edu.cn

Abstract

Herein we report a palladium/TBADT-cocatalyzed dehydrogenative cross-coupling reaction, enabling the synthesis of a variety of 1,4-diketones starting from simple allylic alcohols and aldehydes as the precursors under mild reaction conditions.

Graphical abstract: Synthesis of 1,4-diketones via palladium/photo-cocatalyzed dehydrogenative cross-coupling

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Article information

DOI
https://doi.org/10.1039/D2QO00935H
Article type
Research Article
Submitted
10 Jun 2022
Accepted
14 Jul 2022
First published
14 Jul 2022

Org. Chem. Front., 2022,9, 4649-4653

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Synthesis of 1,4-diketones via palladium/photo-cocatalyzed dehydrogenative cross-coupling

P. Fan, Y. Mao and C. Wang, Org. Chem. Front., 2022, 9, 4649 DOI: 10.1039/D2QO00935H

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