Issue 24, 2022

An indium-based microporous metal–organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Abstract

A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units (SBUs), UTSA-22, was reported and exhibited high methane (CH4) and hydrogen (H2) storage. At 298 K and 65 bar, the total CH4 volumetric uptake of UTSA-22 is 174 cm3(STP) cm−3. Moreover, UTSA-22 shows a high CH4 working capacity of 146 cm3(STP) cm−3 in a pressure range of 5–65 bar at 298 K. In addition, UTSA-22 shows a high H2 gravimetric storage capacity (1.2 wt%) at 298 K and 100 bar.

Graphical abstract: An indium-based microporous metal–organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Supplementary files

Article information

Article type
Research Article
Submitted
10 Sep 2022
Accepted
24 Oct 2022
First published
24 Oct 2022

Inorg. Chem. Front., 2022,9, 6527-6533

Author version available

An indium-based microporous metal–organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

H. Cui, Y. Ye, R. Lin, Y. Shi, Z. A. Alothman, O. Alduhaish, B. Wang, J. Zhang and B. Chen, Inorg. Chem. Front., 2022, 9, 6527 DOI: 10.1039/D2QI01956F

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