Issue 26, 2022

Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

Abstract

Commercially available palladium salts (1–4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl–C[triple bond, length as m-dash]C–C6H4R (a–j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.

Graphical abstract: Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

Supplementary files

Article information

Article type
Communication
Submitted
16 Apr 2022
Accepted
16 Jun 2022
First published
27 Jun 2022

Polym. Chem., 2022,13, 3870-3875

Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

J. Chen, X. Wu, S. Zhang, X. Yan, X. Wu, Q. Cao, H. Xu and X. Li, Polym. Chem., 2022, 13, 3870 DOI: 10.1039/D2PY00490A

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