Nickel(II)–salen or nickel(II)–salphen catalyzed α-alkylation of ketones and nitriles with primary alcohols is reported. Various α-alkylated ketones and nitriles were obtained in high yields through a borrowing hydrogen strategy by using 1–3 mol% of nickel catalyst and a catalytic amount of NaOH (5–10 mol%) under aerobic conditions.
S. Genç, B. Arslan, D. Gülcemal, S. Gülcemal and S. Günnaz, Org. Biomol. Chem., 2022, 20, 9753 DOI: 10.1039/D2OB01787C
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