Acid-mediated phase transition synthesis of stable nanocrystals for high-power LED backlights

Abstract

Perovskite nanocrystals (PNCs) have excellent optical and optoelectronic properties, but their intrinsic instability hampers their practical applications. Herein, stable CsPbBr₃ nanocrystals (NCs) are fabricated with triethylaluminium (TMA, a Lewis acid) and hydrobromic acid by the co-assisted transformation of Cs₄PbBr₆ NCs. TMA forms a cross-linked alumina (AlO_x) encapsulation layer on the nanocrystal surface to suppress the deformation and ion migration. The introduction of hydrobromic acid acts as a binding ligand, and the acidified reaction environment provides conditions for the water-triggered phase transformation of Cs₄PbBr₆ NCs into CsPbBr₃ NCs. The synergistic effect of TMA and hydrobromic acid improves the stability of CsPbBr₃ NCs. The obtained CsPbBr₃ NC film maintains a high photoluminescence (PL) intensity after immersion in water. When stored in the atmosphere for over 30 days, the PL intensity of the CsPbBr₃ NC film hardly decreases. The proposed acid co-assisted phase transformation strategy provides a new avenue for the stabilization of PNCs which exhibits wider application prospects in backlight displays.