Urchin-like hybrid nanostructures of CuOx/Fe2O3 from Cu-mediated pyrolysis of Fe-MOFs for catalytic reduction of organic pollutants

Abstract

MOFs have been widely used as templates to design and construct catalysis materials, such as LDH, metal oxides, and carbon. Herein, we developed a Cu-mediated pyrolysis protocol for the synthesis of urchin-like CuO_x/Fe₂O₃ hybrid nanostructures using Fe-MOFs as the precursor. The hierarchical hybrids were composed of an inner CuO_x-dispersed Fe₂O₃ octahedral matrix covered with radially grown Fe₂O₃ nanorods. This novel hierarchical hybrid nanostructure was generated likely due to the difference in the inward contraction rates between the Cu and Fe species during pyrolysis. Given the structural and compositional benefits, the urchin-like CuO_x/Fe₂O₃ hybrids exhibited outstanding catalytic activity for the chemical reduction of 4-nitrophenol (4-NP) and dyes. Besides, CuO_x/Fe₂O₃ was found to be highly catalytic in the reduction of 4-NP even after 30 consecutive runs, manifesting outstanding durability for continuous operation.