An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

Congjian Ni; Hailong Yu; Ling Liu; Ben Yan; Bingyi Zhang; Xiaoli Ma; Xiuhui Zhang; Zhi Yang

doi:10.1039/D2NJ03136A

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An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst†

Congjian Ni,‡^a Hailong Yu,‡^a Ling Liu,

^a Ben Yan,^a Bingyi Zhang,^a Xiaoli Ma,

*^a Xiuhui Zhang

^a and Zhi Yang*^a

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, P. R. China
E-mail: maxiaoli@bit.edu.cn

Abstract

A cheap and easily available ZnEt₂ is an effective precatalyst, which can be used for the hydroboration reaction of various organic carbonates and esters with HBpin. The preliminary hydroboration reaction mechanism has been investigated via the corresponding DFT calculation.

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Article information

DOI: https://doi.org/10.1039/D2NJ03136A
Article type: Paper
Submitted: 26 Jun 2022
Accepted: 07 Jul 2022
First published: 13 Jul 2022

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New J. Chem., 2022,46, 14635-14641

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An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

C. Ni, H. Yu, L. Liu, B. Yan, B. Zhang, X. Ma, X. Zhang and Z. Yang, New J. Chem., 2022, 46, 14635 DOI: 10.1039/D2NJ03136A

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New Journal of Chemistry

An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst†

Abstract

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An efficient catalytic method for the borohydride reaction of esters using diethylzinc as precatalyst

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