Issue 5, 2022

[1]Rotaxanes based on phosphorylated pillar[5]arenes

Abstract

[1]Rotaxanes based on monosubstituted phosphorus-containing pillar[5]arenes have been synthesized for the first time by the Kabachnik–Fields reaction in good yields. The introduction of the bulky phosphoryl functionalized stopper led to the formation of the [1]rotaxane core. It was found that the [1]rotaxanes were robust and unaffected by changes in the temperature or solvent.

Graphical abstract: [1]Rotaxanes based on phosphorylated pillar[5]arenes

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2021
Accepted
07 Jan 2022
First published
07 Jan 2022

New J. Chem., 2022,46, 2033-2037

[1]Rotaxanes based on phosphorylated pillar[5]arenes

A. Nazarova, P. Padnya, P. J. Cragg and I. Stoikov, New J. Chem., 2022, 46, 2033 DOI: 10.1039/D1NJ05461A

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