Waterproof, breathable and infrared-invisible polyurethane/silica nanofiber membranes for wearable textiles

Abstract

Waterproof and breathable membranes, which have great potential in applications such as membrane distillation, self-cleaning, and multifunctional clothing, have attracted a lot of attention due to their superior performance. Superhydrophobic and infrared-invisible polyurethane (PU)/silica (SiO₂) nanofiber microporous membranes were prepared by facile electrospinning and a hydrothermal-assisted sol–gel method. Compared with pure PU nanofiber membranes, silica nanoparticles act as an adhesion layer, which can provide the rough surface and low surface energy of fibrous membranes. Therefore, the grafted PU/SiO₂ nanofiber membrane was endowed with a good superhydrophobic effect, and its water contact angle (WCA) reached 161°. The nanofiber membrane exhibited comfortable waterproof and breathable properties, in which the air permeability and water vapor transfer rate was 5.18 mm s⁻¹ and 7.85 kg m⁻² d⁻¹, respectively. When the PU/SiO₂ nanofiber membrane was irradiated by infrared light, the surface of the fiber membrane showed a green, low-temperature state. These waterproof and breathable nanofiber membranes with superhydrophobic properties could be used in anti-icing, outdoor concealment, and camouflage applications.