Isovalent anion-induced electrochemical activity of doped Co3V2O8 for oxygen evolution reaction application

Abstract

The activity of an OER electrocatalyst is a strong function of the reaction kinetics at the active sites, which can be influenced by catalytic engineering (e.g., heterostructure, doping, and the addition of cocatalysts). Herein, we report the improved reaction kinetics of cobalt oxide for the OER via the addition of high valence vanadium and thereafter doping with sulphur (S-Co₃V₂O₈). The addition of vanadium increases the oxygen vacancy while the doping of sulphur increases the electronic conductivity of the electrocatalyst. The synergic effect of the oxygen vacancy and electronic conductivity increases the activity of S-Co₃V₂O₈. Furthermore, S-Co₃V₂O₈ showed the least Tafel slope, which showed the activity enhancement towards the oxygen evolution reaction. Moreover, the underlying reaction mechanism is explored by electrochemical impedance spectroscopy, which reveals that the ratio of polarisation resistance to double-layer capacitance is minimum for S-Co₃V₂O₈, indicating the highest activity.