Issue 32, 2022

Polymorphism modulates photoluminescence and magnetic dynamics of mononuclear dysprosium–anthracene complexes

Abstract

Complexes α-Dy(depma)3Cl3 (α-DyCl), β-Dy(depma)3Cl3 (β-DyCl) and β-Dy(depma)3Br3 (β-DyBr) (depma = 9-diethylphosphono-methylanthracene) are reported. α-DyCl and β-DyCl are polymorphs showing distinct magnetic dynamics with energy barriers of 32.3 K and 66.6 K. They also show distinct luminescence properties with emission peaks at 487 nm and 530 nm, respectively.

Graphical abstract: Polymorphism modulates photoluminescence and magnetic dynamics of mononuclear dysprosium–anthracene complexes

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2022
Accepted
19 Jul 2022
First published
21 Jul 2022

Dalton Trans., 2022,51, 12026-12030

Polymorphism modulates photoluminescence and magnetic dynamics of mononuclear dysprosium–anthracene complexes

X. Ma, Y. Guo, X. Huang, G. Wen, S. Bao, Y. Zhang and L. Zheng, Dalton Trans., 2022, 51, 12026 DOI: 10.1039/D2DT01710E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements