A microporous chromium-organic framework fabricated via solvent-assisted metal metathesis for C2H2/CO2 separation

Abstract

Removal of CO₂ or C₂H₄ from C₂H₂ is still a challenging task due to their similar physical–chemical properties. Here, a bifunctional ligand decorated with amino and sulfoxide groups, 5′,5′′′′-sulfonylbis (2′-amino-[1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylic acid) (H₄L), was employed to construct a new microporous iron-organic framework (Fe-MOF) with the formula [(Fe₃O)(L)_1.5(H₂O)₃]_n. This MOF can serve as a parent structure to obtain the isostructural Cr-MOF by solvent-assisted metal metathesis. Furthermore, the gas adsorption and separation performance of these two MOFs were systematically investigated. Compared to Fe-MOF, Cr-MOF shows a moderately higher CO₂, C₂H₂ and C₂H₄ uptake capacity. Additionally, Cr-MOF can selectively adsorb C₂H₂ over CO₂ and C₂H₄. The separation potential towards C₂H₂/C₂H₄ and C₂H₂/CO₂ was further established via IAST calculations of mixture adsorption equilibrium. IAST selectivity values of Cr-MOF are 3.4 for C₂H₂/C₂H₄ and 6.9 for C₂H₂/CO₂ at 298 K and initial pressure, indicating its potential C₂H₂ separation ability.