Ni2P NPs loaded on methylthio-functionalized UiO-66 for boosting visible-light-driven photocatalytic H2 production

Abstract

The UiO-66 family shows promising photocatalytic prospects in water splitting for hydrogen evolution under visible light irradiation due to its suitable band gap and adequate active sites. In this work, novel Ni₂P/UiO-66-(SCH₃)₂ composites were prepared by a simple solvothermal method. These as-synthesized samples were fully characterized by XRD, SEM, TEM, HRTEM, EDS, and XPS methods. The effectiveness of visible light driven photocatalytic water-splitting to produce hydrogen was investigated in the presence of sacrificial agents. The results showed that the optimal hydrogen yield of 5 wt% Ni₂P/UiO-66-(SCH₃)₂ is 3724.22 μmol g⁻¹ h⁻¹, reaching almost 187 times that of pristine UiO-66-(SCH₃)₂ (19.93 μmol g⁻¹ h⁻¹). Meanwhile, long term cycling stability tests also showed that Ni₂P/UiO-66-(SCH₃)₂ composites present an excellent photocatalytic H₂ production stability. Photoelectrochemical performance analysis revealed that the high catalytic activity of the composite materials could be associated with the synergistic effect of UiO-66-(SCH₃)₂ and Ni₂P. Light stimulates UiO-66-(SCH₃)₂ to generate electrons and holes, and Ni₂P as a cocatalyst could effectively transmit electrons and boost photogenerated charge separation. This work provides a reference for exploring UiO-66 family catalysts with good catalytic activity.