Co, Mn co-doped Fe9S11@Ni9S8 supported on nickel foam as a high efficiency electrocatalyst for the oxygen evolution reaction and urea oxidation reaction

Abstract

The Earth's fossil resources will be exhausted soon, so it is urgent to find clean and efficient new energy for replacing fossil resources. Hydrogen energy is gradually attracting the attention of the public and electrolysis of water is considered to be one of the important means of hydrogen production because of its simplicity and convenience. In this paper, a hydrothermal method for the synthesis of a Co and Mn co-doped bimetallic sulfide Fe₉S₁₁@Ni₉S₈ electrocatalyst is proposed for the first time. The prepared Co-Mn-Fe₉S₁₁@Ni₉S₈/NF electrocatalyst exhibits excellent electrocatalytic activity for the oxygen evolution reaction (OER) and urea oxidation reaction (UOR). It can provide a current density of 10 mA cm⁻² with only 193 mV overpotential for the OER and a current density of 10 mA cm⁻² with only 1.33 V potential for the UOR, which are far superior to those of most reported electrocatalysts. What is noteworthy is that the unique nanoflower structure of Co-Mn-Fe₉S₁₁@Ni₉S₈/NF increases the specific surface area of the material and the introduction of Co and Mn ions promotes the formation of high valence state Ni and Fe and enhances the charge transfer rate. The density functional theory (DFT) calculation shows that the in situ generated Co-Mn-Fe-NiOOH material derived from Co-Mn-Fe₉S₁₁@Ni₉S₈ exhibits the best water adsorption energy and the best electrical conductivity, thus improving the catalytic performance of the material. This work provided a new idea for the development of bimetallic cation doped electrocatalysts with high efficiency and low cost.