A new dimethyl(phenyl)silylborane having a naphthalene-1,8-diaminato (dan) substituent on the boron center, PhMe2Si–B(dan), was synthesized. Owing to the diminished boron Lewis acidity, it is highly stable toward air. Synthetic application of the silylborane to catalytic silylboration and silylation of alkynes is also described.
H. Yoshida, Y. Izumi, Y. Hiraoka, K. Nakanishi, M. Nakamoto, S. Hatano and M. Abe, Dalton Trans., 2022, 51, 6543 DOI: 10.1039/D2DT00962E
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