Issue 27, 2022
From the journal:

Dalton Transactions

Luminescent early-late-hetero-tetranuclear group IV – Au(i) bisamidinate complexes†

Cedric Uhlmann, ORCID logo a   Thomas J. Feuerstein, ORCID logo a   Tim P. Seifert,a   André P. Jung, ORCID logo a   Michael T. Gamer, ORCID logo a   Ralf Köppe,a   Sergei Lebedkin,b   Manfred M. Kappesbc  and  Peter W. Roesky ORCID logo *a  

* Corresponding authors

a Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu

b Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

c Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany

Abstract

The versatile metalloligand [{HC[triple bond, length as m-dash]CC(NDipp)2}2Au2] (dipp = 2,6-diisopropylphenyl) was converted into early-late heterotetrametallic complexes [{ClCp2MC[triple bond, length as m-dash]CC(NDipp)2}2Au2] (M = Ti, Zr). These compounds show photoluminescence with either remarkably different (Ti) or similar (Zr) features as compared to related solely coinage metal containing acetylide amidinate complexes.

Graphical abstract: Luminescent early-late-hetero-tetranuclear group IV – Au(i) bisamidinate complexes

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Article information

DOI
https://doi.org/10.1039/D2DT00458E
Article type
Communication
Submitted
14 Feb 2022
Accepted
04 Jun 2022
First published
01 Jul 2022
This article is Open Access
Creative Commons BY license

Dalton Trans., 2022,51, 10357-10360

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Luminescent early-late-hetero-tetranuclear group IV – Au(I) bisamidinate complexes

C. Uhlmann, T. J. Feuerstein, T. P. Seifert, A. P. Jung, M. T. Gamer, R. Köppe, S. Lebedkin, M. M. Kappes and P. W. Roesky, Dalton Trans., 2022, 51, 10357 DOI: 10.1039/D2DT00458E

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