Issue 16, 2022

Inorganic acid influenced formation of Ti26 and Ti44 oxysulfate clusters with toroidal and capsule structures

Abstract

We herein report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters by ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO42−vs. pseudo-tetrahedral PO33−) shows an interesting influence on cluster structure formation.

Graphical abstract: Inorganic acid influenced formation of Ti26 and Ti44 oxysulfate clusters with toroidal and capsule structures

Supplementary files

Article information

Article type
Communication
Submitted
14 Jan 2022
Accepted
23 Mar 2022
First published
24 Mar 2022

Dalton Trans., 2022,51, 6162-6165

Inorganic acid influenced formation of Ti26 and Ti44 oxysulfate clusters with toroidal and capsule structures

K. Chintakrinda, N. Narayanam, G. Chen, F. Wang, J. Zhang and L. Zhang, Dalton Trans., 2022, 51, 6162 DOI: 10.1039/D2DT00119E

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