Inorganic acid influenced formation of Ti26 and Ti44 oxysulfate clusters with toroidal and capsule structures

Kalpana Chintakrinda; Nagaraju Narayanam; Guang-Hui Chen; Fei Wang; Jian Zhang; Lei Zhang

doi:10.1039/D2DT00119E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Inorganic acid influenced formation of Ti₂₆ and Ti₄₄ oxysulfate clusters with toroidal and capsule structures†

Kalpana Chintakrinda,^ab Nagaraju Narayanam,^a Guang-Hui Chen,^a Fei Wang,

^a Jian Zhang

^a and Lei Zhang

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: LZhang@fjirsm.ac.cn

^b University of Chinese Academy of Science, Beijing, P. R. China

Abstract

We herein report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters by ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO₄²⁻vs. pseudo-tetrahedral PO₃³⁻) shows an interesting influence on cluster structure formation.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2DT00119E
Article type: Communication
Submitted: 14 Jan 2022
Accepted: 23 Mar 2022
First published: 24 Mar 2022

Download Citation

Dalton Trans., 2022,51, 6162-6165

Permissions

Request permissions

Inorganic acid influenced formation of Ti₂₆ and Ti₄₄ oxysulfate clusters with toroidal and capsule structures

K. Chintakrinda, N. Narayanam, G. Chen, F. Wang, J. Zhang and L. Zhang, Dalton Trans., 2022, 51, 6162 DOI: 10.1039/D2DT00119E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions