Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide

Grégoire Le Corre; Hansjörg Grützmacher

doi:10.1039/D1DT04223H

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Simple conversion of trisodium phosphide, Na₃P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide†

Grégoire Le Corre

^a and Hansjörg Grützmacher

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Applied Biosciences ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland
E-mail: hgruetzmacher@ethz.ch

Abstract

A reaction of trisodium phosphide (Na₃P) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.

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Article information

DOI: https://doi.org/10.1039/D1DT04223H
Article type: Paper
Submitted: 15 Dec 2021
Accepted: 18 Jan 2022
First published: 19 Jan 2022
This article is Open Access

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Dalton Trans., 2022,51, 3497-3501

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Simple conversion of trisodium phosphide, Na₃P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide

G. Le Corre and H. Grützmacher, Dalton Trans., 2022, 51, 3497 DOI: 10.1039/D1DT04223H

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