Issue 30, 2022

Can an alkalide act as a perfect Lewis base?

Abstract

The Lewis basic character of alkali metals forming donor–acceptor complexes is a very rare phenomenon. No Lewis adduct with an alkalide as the Lewis basic centre has ever been reported. Herein, we theoretically designed EXH2 (E = Li, Na, K; X = Be, Mg, Ca) clusters which represent the first true example of Lewis adducts with alkalides as the two-electron donor basic sites. Our high level ab initio calculations reveal the formation of an unprecedented E: → XH2 donor–acceptor interaction. Topological analysis within the realm of the electron localization function confirms this bonding scenario. The bonding scenario is exactly replicated in all the clusters, rendering support to our proposal. The calculated bond dissociation energies are significant, suggesting their possible spectroscopic identification.

Graphical abstract: Can an alkalide act as a perfect Lewis base?

Supplementary files

Article information

Article type
Paper
Submitted
20 Jun 2022
Accepted
11 Jul 2022
First published
11 Jul 2022

Phys. Chem. Chem. Phys., 2022,24, 18144-18149

Can an alkalide act as a perfect Lewis base?

A. J. Kalita, S. K. Purkayastha, K. Sarmah and A. K. Guha, Phys. Chem. Chem. Phys., 2022, 24, 18144 DOI: 10.1039/D2CP02800J

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