Issue 36, 2022

Reversible synthesis of structured MOF-to-metal oxide nanorods

Abstract

Aluminum framework MIL-53(Al) acquires uniform, one-dimensional crystal growth when produced from insoluble metal sources. Pyrolysis of this structured MIL-53(Al) forms new alumina-based nanorods that extend up to 5 μm in one dimension without external templates or structure–direction and serve as growth templates for regenerative MOF production.

Graphical abstract: Reversible synthesis of structured MOF-to-metal oxide nanorods

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2022
Accepted
21 Aug 2022
First published
31 Aug 2022

CrystEngComm, 2022,24, 6309-6314

Author version available

Reversible synthesis of structured MOF-to-metal oxide nanorods

C. M. Moran, J. N. Joshi, H. P. Feininger and K. S. Walton, CrystEngComm, 2022, 24, 6309 DOI: 10.1039/D2CE00969B

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