Issue 24, 2022
From the journal:

CrystEngComm

A Hg(i) corrugated sheet assembled by auxiliary dioxole groups and Hg⋯π interactions†

Francisco Sánchez-Férez, ORCID logo a   Xavier Solans-Monfort, ORCID logo a   Teresa Calvet, ORCID logo b   Mercè Font-Bardia ORCID logo c  and  Josefina Pons ORCID logo *a  

* Corresponding authors

a Departament de Química, Universitat Autònoma de Barcelona, 08193-Bellaterra, Barcelona, Spain
E-mail: josefina.pons@uab.es

b Departament de Mineralogia, Petrologia i Geologia Aplicada, Universitat de Barcelona, Martí i Franquès s/n, 08028 Barcelona, Spain

c Unitat de Difracció de Raig-X, Centres Científics i Tecnològics de la Universitat de Barcelona (CCiTUB), Universitat de Barcelona, Solé i Sabarís, 1-3, 08028 Barcelona, Spain

Abstract

The formation of a new double-stranded staircase Hg(I) supramolecular assembly is reported. It is arranged into 2D corrugated sheets supported by Hg(I)⋯Odioxole and Hg⋯π interactions, resulting from the comproportionation reaction between Hg(II) and Hg(0) species in DMF as a solvent.

Graphical abstract: A Hg(i) corrugated sheet assembled by auxiliary dioxole groups and Hg⋯π interactions

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Article information

DOI
https://doi.org/10.1039/D2CE00347C
Article type
Communication
Submitted
11 Mar 2022
Accepted
05 May 2022
First published
07 Jun 2022

CrystEngComm, 2022,24, 4351-4355

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A Hg(I) corrugated sheet assembled by auxiliary dioxole groups and Hg⋯π interactions

F. Sánchez-Férez, X. Solans-Monfort, T. Calvet, M. Font-Bardia and J. Pons, CrystEngComm, 2022, 24, 4351 DOI: 10.1039/D2CE00347C

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