Issue 12, 2022

Coordination polymers derived from alkali metal complexes of redox-active ligands

Abstract

Treatment of toluene solutions of (dpp-bian)M (dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene; M = Li, Na, K) with 4,4′-bipyridine (4,4′-bipy) affords coordination polymers [(dpp-bian)Li(4,4′-bipy)]n (1), [(dpp-bian)Na(4,4′-bipy)2]n (2) and [(dpp-bian)K(4,4′-bipy)]n (3). Compounds 1–3 have been characterized by elemental analysis and thermogravimetry (TGA) as well as IR, UV-vis and ESR spectroscopy. According to single crystal X-ray analysis, products 1 and 2 present 1D coordination polymers, while product 3 reveals a 2D architecture.

Graphical abstract: Coordination polymers derived from alkali metal complexes of redox-active ligands

Supplementary files

Article information

Article type
Paper
Submitted
22 Dec 2021
Accepted
16 Feb 2022
First published
02 Mar 2022

CrystEngComm, 2022,24, 2297-2304

Coordination polymers derived from alkali metal complexes of redox-active ligands

N. L. Bazyakina, M. V. Moskalev, A. V. Cherkasov, V. M. Makarov and I. L. Fedushkin, CrystEngComm, 2022, 24, 2297 DOI: 10.1039/D1CE01698A

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