Novel D–π–A-type fluorinated tolane with a diphenylamino group was synthesized, yielding two crystal polymorphisms induced by fluorine atoms in the tolane scaffold. The two crystal polymorphisms exhibited distinct photophysical behavior, with one displaying a significant photoluminescence behavior change upon the application of external stimuli.
S. Yamada, K. Kobayashi, M. Morita and T. Konno, CrystEngComm, 2022, 24, 936 DOI: 10.1039/D1CE01671G
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