A tetradentate ligand, 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (TPPE), was adopted to construct a two-dimensional coordination polymer that incorporated valence tautomerism and luminescence, and the synergistic effect arising from energy transfer from TPPE to the semiquinone moieties was experimentally and theoretically uncovered.
W. Liu, J. Hu, M. Yu, J. Xue, Z. Liu, J. Wang and J. Tao, Chem. Commun., 2022, 58, 13903 DOI: 10.1039/D2CC05883A
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