Issue 92, 2022
From the journal:

Chemical Communications

A host–guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols†

Jinyang Wu,‡a   Youran Luo,‡a   Lingxuan Chen,a   Xuan Sun,a   Xinnan Chen,a   Song Qin, ORCID logo a   Wen Feng, ORCID logo *a   Xiaowei Li ORCID logo *a  and  Lihua Yuan ORCID logo *a  

* Corresponding authors

a Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, College of Chemistry, Sichuan University, Chengdu, China
E-mail: lhyuan@scu.edu.cn, wfeng9510@scu.edu.cn, lixw@scu.edu.cn

Abstract

Host–guest complexation using hydrogen-bonded macrocycles was found to enable activation of the Bobbitt oxidant reagent, which greatly facilitates the highly efficient oxidation of unactivated primary alcohols. This work provides a complementary approach to the activation of Bobbitt's salt with shape-persistent macrocycles in supramolecular catalysis.

Graphical abstract: A host–guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols

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Article information

DOI
https://doi.org/10.1039/D2CC05027G
Article type
Communication
Submitted
12 Sep 2022
Accepted
21 Oct 2022
First published
24 Oct 2022

Chem. Commun., 2022,58, 12867-12870

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A host–guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols

J. Wu, Y. Luo, L. Chen, X. Sun, X. Chen, S. Qin, W. Feng, X. Li and L. Yuan, Chem. Commun., 2022, 58, 12867 DOI: 10.1039/D2CC05027G

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