Issue 81, 2022

Multivariate zeolitic imidazolate frameworks with an inverting trend in flexibility

Abstract

Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption–desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure trend—in which the step pressure decreases and then increases again with increasing mixed linker concentration—is observed, highlighting how linker substitution modifies the energetic landscape of framework flexibility.

Graphical abstract: Multivariate zeolitic imidazolate frameworks with an inverting trend in flexibility

Supplementary files

Article information

Article type
Communication
Submitted
05 Aug 2022
Accepted
09 Sep 2022
First published
22 Sep 2022

Chem. Commun., 2022,58, 11394-11397

Multivariate zeolitic imidazolate frameworks with an inverting trend in flexibility

A. Halder, R. A. Klein, R. Lively and C. M. McGuirk, Chem. Commun., 2022, 58, 11394 DOI: 10.1039/D2CC04362A

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