Issue 76, 2022
From the journal:

Chemical Communications

Diverse reactivity of a magnesium silanide toward ketones†

Bibian Okokhere-Edeghoghon, ORCID logo a   Michael S. Hill, ORCID logo *a   Mary F. Mahona  and  Claire L. McMullin ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: msh27@bath.ac.uk, cm2025@bath.ac.uk

Abstract

The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.

Graphical abstract: Diverse reactivity of a magnesium silanide toward ketones

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Article information

DOI
https://doi.org/10.1039/D2CC03966D
Article type
Communication
Submitted
15 Jul 2022
Accepted
30 Aug 2022
First published
30 Aug 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 10711-10714

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Diverse reactivity of a magnesium silanide toward ketones

B. Okokhere-Edeghoghon, M. S. Hill, M. F. Mahon and C. L. McMullin, Chem. Commun., 2022, 58, 10711 DOI: 10.1039/D2CC03966D

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