Air-stable aryl derivatives of pentafluoroorthotellurate

Abstract

We report on two different sets of air-stable derivatives of pentafluoroorthotellurate containing fluorinated and non-fluorinated aryl groups. The acid cis-PhTeF₄OH was obtained in gram scale and further transformed to Ag[cis-PhTeF₄O], which was used as a cis-PhTeF₄O transfer reagent to obtain [PPh₄][cis-PhTeF₄O]. Furthermore, the synthesis of trans-(C₆F₅)₂TeF₃OH was achieved by a selective hydrolysis of trans-(C₆F₅)₂TeF₄ in the presence of KF and subsequent protonation by aHF. Quantum-chemical calculations show a higher acidity and robustness against fluoride abstraction for trans-(C₆F₅)₂TeF₃OH compared to cis-PhTeF₄OH.