Issue 87, 2022
From the journal:

Chemical Communications

Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes†

Guo Shen,a   Shaomin Fu ORCID logo *a  and  Bo Liu ORCID logo *a  

* Corresponding authors

a Key Laboratory of Green Chemistry &Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, China
E-mail: chembliu@scu.edu.cn, fsm09@aliyun.com

Abstract

An oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes is developed. This protocol is operationally simple and atom economical. The reaction shows broad functional group tolerance, such as ketones, amides, esters, epoxides, alcohols and carboxylic acids. Mono-substituted and geminally substituted alkenes could be chemoselectively hydrosilylated.

Graphical abstract: Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes

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Article information

DOI
https://doi.org/10.1039/D2CC03917F
Article type
Communication
Submitted
13 Jul 2022
Accepted
06 Oct 2022
First published
06 Oct 2022

Chem. Commun., 2022,58, 12204-12207

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Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes

G. Shen, S. Fu and B. Liu, Chem. Commun., 2022, 58, 12204 DOI: 10.1039/D2CC03917F

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