Issue 81, 2022

Heteroleptic copper(i) charge-transfer chromophores with panchromatic absorption

Abstract

Four new heteroleptic bis-chelate Cu(I) complexes showing panchromatic visible absorption are described here. With this heteroleptic design, we demonstrate that the energy levels of the spatially separated HOMO and LUMO can be independently and systematically controlled via ligand modification, with charge-transfer absorption bands throughout the visible and NIR regions that cover a wider range than typical Cu(I) chromophores.

Graphical abstract: Heteroleptic copper(i) charge-transfer chromophores with panchromatic absorption

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2022
Accepted
14 Sep 2022
First published
23 Sep 2022

Chem. Commun., 2022,58, 11446-11449

Author version available

Heteroleptic copper(I) charge-transfer chromophores with panchromatic absorption

D. Kim, T. G. Gray and T. S. Teets, Chem. Commun., 2022, 58, 11446 DOI: 10.1039/D2CC03873K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements