Issue 74, 2022
From the journal:

Chemical Communications

A crystalline cyclic (alkyl)(amino)carbene with a 1,1′-ferrocenylene backbone†‡

Julia Volk,a   Myron Heinz,b   Michael Leibold,a   Clemens Bruhn,a   Tobias Bens,c   Biprajit Sarkar, ORCID logo c   Max C. Holthausen ORCID logo b  and  Ulrich Siemeling ORCID logo *a  

* Corresponding authors

a Institut für Chemie, Universität Kassel, Heinrich-Plett-Straße 40, 34132 Kassel, Germany
E-mail: siemeling@uni-kassel.de

b Institut für Anorganische und Analytische Chemie, Goethe-Universität, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany

c Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 50659 Stuttgart, Germany

Abstract

Cyclic (alkyl)(amino)carbenes with a 1,1′-ferrocenylene backbone (fcCAACs) are established as an original family by the preparation of a crystalline congener. The Ccarbene bond angle is unprecedentedly wide for a CAAC, causing an exceptionally pronounced ambiphilicity. The redox-active backbone opens the door to unconventional metalloradicals and oligoradicals.

Graphical abstract: A crystalline cyclic (alkyl)(amino)carbene with a 1,1′-ferrocenylene backbone

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Article information

DOI
https://doi.org/10.1039/D2CC03871D
Article type
Communication
Submitted
11 Jul 2022
Accepted
19 Aug 2022
First published
19 Aug 2022

Chem. Commun., 2022,58, 10396-10399

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A crystalline cyclic (alkyl)(amino)carbene with a 1,1′-ferrocenylene backbone

J. Volk, M. Heinz, M. Leibold, C. Bruhn, T. Bens, B. Sarkar, M. C. Holthausen and U. Siemeling, Chem. Commun., 2022, 58, 10396 DOI: 10.1039/D2CC03871D

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