Issue 63, 2022

Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions

Abstract

Photocatalyzed oxidative decarboxylation of oxamic acids under near-infrared irradiation using Os(bptpy)2(PF6)2 as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.

Graphical abstract: Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions

Supplementary files

Article information

Article type
Communication
Submitted
03 Jun 2022
Accepted
07 Jul 2022
First published
08 Jul 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 8802-8805

Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions

I. M. Ogbu, D. M. Bassani, F. Robert and Y. Landais, Chem. Commun., 2022, 58, 8802 DOI: 10.1039/D2CC03155H

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