Issue 55, 2022
From the journal:

Chemical Communications

Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets†

Jinjiang Wu,ac   Guo-Lu Wang,b   Zhenhua Zhu,ad   Chen Zhao, ORCID logo ac   Xiao-Lei Li, ORCID logo a   Yi-Quan Zhang ORCID logo *b  and  Jinkui Tang ORCID logo *ac  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
E-mail: tang@ciac.ac.cn

b Jiangsu Key Lab for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China
E-mail: zhangyiquan@njnu.edu.cn

c School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China

d University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Terminal fluoride ligands generate strong magnetic anisotropy in air-stable chiral dysprosium enantiomers supported by a bulky equatorial macrocycle, exhibiting a typical zero-field single-molecule magnet behaviour.

Graphical abstract: Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets

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Article information

DOI
https://doi.org/10.1039/D2CC02570A
Article type
Communication
Submitted
06 May 2022
Accepted
06 Jun 2022
First published
07 Jun 2022

Chem. Commun., 2022,58, 7638-7641

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Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets

J. Wu, G. Wang, Z. Zhu, C. Zhao, X. Li, Y. Zhang and J. Tang, Chem. Commun., 2022, 58, 7638 DOI: 10.1039/D2CC02570A

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