Ferroelectric coordination metal complexes based on structural and electron dynamics

Abstract

Ferroelectrics that display electrically invertible polarisation are attractive materials because of their potential for wide-ranging applications. To date, considerable effort has thus been devoted towards developing ferroelectric materials, particularly those comprising organic/inorganic compounds. In these systems, structural dynamics such as atomic displacement and reorientation of polar ions/molecules play a key role in the generation of reversible spontaneous polarisation. Although there are many reports concerned with organic/inorganic ferroelectrics, ferroelectrics based on coordination metal complexes have been largely unexplored despite their often unique electronic and spin state properties. In this feature article, we discuss recent progress involving coordination metal complex-based ferroelectrics where the reversible polarisation originates not only from structural dynamics (represented by proton transfer, molecular motion, and liquid crystalline behaviour) but also from electron dynamics (represented by electron transfer and spin crossover phenomena) occurring at the metal centre. Furthermore, unique synergy effects (i.e. magnetoelectric coupling) resulting from the structural and electron dynamics are described. We believe that this review pertaining to ferroelectric coordination metal complexes provides new insights for fabricating further advanced functional materials such as multiferroics and spintronics.