Electrocatalytic nitrate reduction to ammonia via amorphous cobalt boride

Abstract

Electrocatalytic nitrate reduction reaction (NitRR) is an energy-saving and environmentally benign approach to synthesizing ammonia under ambient conditions. However, the development of noble metal-free catalysts with high activity and selectivity is still a significant challenge. In this study, uniformly dispersed amorphous CoB_x nanoparticles supported on carbon paper were synthesized VIA a simple wet chemical reduction method. As an efficient nitrate reduction electrocatalyst, CoB_x exhibited a maximum faradaic efficiency of 94.00 ± 1.67% and a yield rate of up to 0.787 ± 0.028 mmol h⁻¹ cm⁻² for ammonia production. The enhanced NitRR performance could be attributed to a partial electron transfer from B to Co, which is necessary for optimizing the adsorption energies of the reaction intermediates and facilitating electron transport. Thus, selective and cost-effective electroreduction of nitrates to ammonia can be achieved using CoB_x nanoparticles.