Uniform Wrapping of Copper(I) Oxide Nanocubes by Self-Controlled Copper-Catalyzed Azide–Alkyne Cycloaddition toward Selective Carbon Dioxide Electrocatalysis

Abstract

We wrapped copper(I) oxide nanocubes with an extremely uniform organic layer grown by self-controlled, Cu-mediated catalysis. The layer held copper within the initial cubic structure during its use as a CO2 reduction electrocatalyst, resulting in high CO2 reduction selectivity by strong suppression of hydrogen evolution because of exclusion of water from the surface.

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Article information

Article type
Communication
Submitted
08 Apr 2022
Accepted
22 Jun 2022
First published
23 Jun 2022

Chem. Commun., 2022, Accepted Manuscript

Uniform Wrapping of Copper(I) Oxide Nanocubes by Self-Controlled Copper-Catalyzed Azide–Alkyne Cycloaddition toward Selective Carbon Dioxide Electrocatalysis

T. Umeda, T. Kurome, A. Sakamoto, K. Kubo, T. Mizuta, S. U. Son and S. Kume, Chem. Commun., 2022, Accepted Manuscript , DOI: 10.1039/D2CC02017C

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