Bisstibane–distibane conversion via consecutive single-electron oxidation and reduction reaction

Abstract

peri-Substituted naphthalene complexes (Trip₂Pn)₂Naph (Pn = Sb 1, Bi 2) were synthesised and their redox behaviour investigated. Oxidation of 1 with [Fc][BAr^F] (BAr^F = B(C₆F₅)₄) yielded [(Trip₂Sb)(TripSb)Naph][BAr^F] (3) containing the stibane-coordinated stibenium cation [(Trip₂Sb)(TripSb)Naph]⁺. Subsequent reduction of 3 with KC₈ yielded distibane (TripSb)₂Naph (4). 1–4 were characterised by NMR (¹H, ¹³C) and IR spectroscopy as well as single-crystal X-ray diffraction (sc-XRD), while their electronic structures were analysed by quantum chemical computations.