Construction and two-dimensional assembly of double-shell Na@Sn6L6@Sn3L3 clusters through tetrahedral citrate ligands

Yu Zhu; Dongsheng Li; Jian Zhang; Lei Zhang

doi:10.1039/D2CC01824A

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Construction and two-dimensional assembly of double-shell Na@Sn₆L₆@Sn₃L₃ clusters through tetrahedral citrate ligands†

Yu Zhu,^ab Dongsheng Li,

*^a Jian Zhang

^b and Lei Zhang

*^b

Author affiliations

* Corresponding authors

^a Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering, China Three Gorges University, Yichang, Hubei 443002, P. R. China
E-mail: lidongsheng1@126.com

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: LZhang@fjirsm.ac.cn

Abstract

Herein we report double-shell Na@Sn₆L₆@Sn₃L₃ clusters and their further assembly into a 2D layer, which belongs to a rare Sn-oxo coordination cage-based extended structure. Tetrahedral citrate ligands with multiple coordination sites play key roles in such hierarchical assembly.

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Article information

DOI: https://doi.org/10.1039/D2CC01824A
Article type: Communication
Submitted: 30 Mar 2022
Accepted: 07 Apr 2022
First published: 14 Apr 2022

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Chem. Commun., 2022,58, 5650-5652

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Construction and two-dimensional assembly of double-shell Na@Sn₆L₆@Sn₃L₃ clusters through tetrahedral citrate ligands

Y. Zhu, D. Li, J. Zhang and L. Zhang, Chem. Commun., 2022, 58, 5650 DOI: 10.1039/D2CC01824A

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Chemical Communications