Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines

Erlin Yue; Andrey Petrov; Daniel S. Frost; Lea Dettling; Lawrence Conrad; Friedrich Wossidlo; Nathan T. Coles; Manuela Weber; Christian Müller

doi:10.1039/D2CC01817A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ³-phosphinines†‡

Erlin Yue,

§^ab Andrey Petrov,§^a Daniel S. Frost,

^a Lea Dettling,

^a Lawrence Conrad,^a Friedrich Wossidlo,^a Nathan T. Coles,^a Manuela Weber^a and Christian Müller

*^a

Author affiliations

* Corresponding authors

^a Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, 14195 Berlin, Germany
E-mail: c.mueller@fu-berlin.de

^b Shaanxi Key Laboratory of Chemical Reaction Engineering, Key Laboratory of New Energy & New Functional Materials, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, People's Republic of China
E-mail: yueerlin@yau.edu.cn

Abstract

The reaction of 2,4,6-triaryl-λ³-phosphinine-Cr(CO)₃-π-complexes with [Rh(COD)₂]BF₄ leads to unusual diamagnetic Rh⁰-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e⁻-ligand towards the Rh₂(CO)₂ core. These compounds represent a missing coordination mode for the aromatic 6-membered phosphorus heterocycle.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2CC01817A
Article type: Communication
Submitted: 30 Mar 2022
Accepted: 13 Apr 2022
First published: 13 Apr 2022
This article is Open Access

Download Citation

Chem. Commun., 2022,58, 6184-6187

Permissions

Request permissions

Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ³-phosphinines

E. Yue, A. Petrov, D. S. Frost, L. Dettling, L. Conrad, F. Wossidlo, N. T. Coles, M. Weber and C. Müller, Chem. Commun., 2022, 58, 6184 DOI: 10.1039/D2CC01817A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications