Issue 52, 2022

B,N-doped PAHs from tridentate ‘Defects’ – a bottom-up convergent approach for π-extended systems

Abstract

A logical construction of monomeric subunits armed with the carbonyl functionality allowing post-synthetic reactivity leads to the convergent formation of π-extended defected units activated with BBr3. The kinetic or thermodynamic control entraps either the pyrido[2,3-g]quinoline or the 4,7-phenanthroline motifs doped with boron(III), which deeply modulates the optical properties.

Graphical abstract: B,N-doped PAHs from tridentate ‘Defects’ – a bottom-up convergent approach for π-extended systems

Supplementary files

Article information

Article type
Communication
Submitted
29 Mar 2022
Accepted
24 May 2022
First published
25 May 2022

Chem. Commun., 2022,58, 7269-7272

B,N-doped PAHs from tridentate ‘Defects’ – a bottom-up convergent approach for π-extended systems

M. Farinone, M. Kijewska, J. Cybińska, M. Siczek and M. Pawlicki, Chem. Commun., 2022, 58, 7269 DOI: 10.1039/D2CC01801B

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