Issue 32, 2022
From the journal:

Chemical Communications

Regiospecific construction of m-alkenyl benzaldehyde from β-bromoenal and vinyl borate†

Xiaolan Xin,‡a   Yilin Liu,‡a   Lu Zhou,a   You Li,a   Han Luo,a   Lei Liu,a   Ruopeng Bai, ORCID logo a   Yu Lan ORCID logo *ab  and  Baosheng Li ORCID logo *a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, 174 Shazheng Street, Chongqing, China
E-mail: lanyu@cqu.edu.cn, libs@cqu.edu.cn

b Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Abstract

Herein, we report a Pd-catalyzed regiospecific cycloaromatization of β-bromoenal and vinyl borate esters to synthesize m-alkenyl substituted benzaldehydes. This allows the construction of complex molecules from simple materials, which may be useful in the search for new optical materials.

Graphical abstract: Regiospecific construction of m-alkenyl benzaldehyde from β-bromoenal and vinyl borate

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Article information

DOI
https://doi.org/10.1039/D2CC01441F
Article type
Communication
Submitted
02 Feb 2022
Accepted
17 Mar 2022
First published
19 Mar 2022

Chem. Commun., 2022,58, 4989-4992

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Regiospecific construction of m-alkenyl benzaldehyde from β-bromoenal and vinyl borate

X. Xin, Y. Liu, L. Zhou, Y. Li, H. Luo, L. Liu, R. Bai, Y. Lan and B. Li, Chem. Commun., 2022, 58, 4989 DOI: 10.1039/D2CC01441F

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