Issue 36, 2022

Electricity mediated [3+2]-cycloaddition of N-sulfonylcyclopropanes with olefins via N-centered radical intermediates: access to cyclopentane analogs

Abstract

An external oxidant free electrochemical strategy is designed towards the β-scission of strained C–C bonds in cyclopropylamine. Moreover, the mechanistic studies ascertained that the methodology encompasses the N-center radical (NCRs) route and provides access to di- or tri-substituted cyclopentane analogs.

Graphical abstract: Electricity mediated [3+2]-cycloaddition of N-sulfonylcyclopropanes with olefins via N-centered radical intermediates: access to cyclopentane analogs

Supplementary files

Article information

Article type
Communication
Submitted
07 Feb 2022
Accepted
22 Mar 2022
First published
30 Mar 2022

Chem. Commun., 2022,58, 5459-5462

Electricity mediated [3+2]-cycloaddition of N-sulfonylcyclopropanes with olefins via N-centered radical intermediates: access to cyclopentane analogs

D. Saha, I. M. Taily, N. Banerjee and P. Banerjee, Chem. Commun., 2022, 58, 5459 DOI: 10.1039/D2CC00761D

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