Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities

Abstract

Two unprecedented Sn/Cd-oxo clusters, including non-alkyltin Sn^II₂Sn^IV₂Cd₄ and alkyltin Sn^IV₂Cd₁₂, have been constructed using triethanolamine and inorganic or organic tin precursors, respectively. Comparative electrocatalytic CO₂ reduction experiments show that the presence of non-alkyl and variable-valent tin centres could greatly improve the catalytic activities.