A multidentate polymer microreactor route for green mass fabrication of mesoporous NaYF4 clusters

Yameng Li; Xiaozeng Zhang; Zhicong Chao; Minglong Gan; Jinsheng Liao; Xinyu Ye; Weixiong You; Junxiang Fu; Herui Wen

doi:10.1039/D1CC06255G

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A multidentate polymer microreactor route for green mass fabrication of mesoporous NaYF₄ clusters†

Yameng Li,

^ab Xiaozeng Zhang,^ab Zhicong Chao,^ab Minglong Gan,^ab Jinsheng Liao,

^ab Xinyu Ye,

^ac Weixiong You,

^ac Junxiang Fu

*^ab and Herui Wen

*^ab

Author affiliations

* Corresponding authors

^a Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou, P. R. China
E-mail: brxw@qq.com, wenherui63@163.com

^b Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Ganzhou, P. R. China

^c Key Laboratory of Rare Earth Luminescence Materials and Devices of Jiangxi Province, Ganzhou, P. R. China

Abstract

We report a “multidentate polymer microreactor” method for the creation of secondary structures of colloidal nanocrystals. Using NaYF₄:Yb,Er as an example, we demonstrate that the use of sodium polyacrylate (PAAS) as a “multidentate polymer microreactor” allows the controllable growth of primary nanocrystals and induces aggregation of the nanocrystals into well-defined mesoporous clusters.

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Article information

DOI: https://doi.org/10.1039/D1CC06255G
Article type: Communication
Submitted: 05 Nov 2021
Accepted: 29 Dec 2021
First published: 30 Dec 2021

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Chem. Commun., 2022,58, 1764-1767

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A multidentate polymer microreactor route for green mass fabrication of mesoporous NaYF₄ clusters

Y. Li, X. Zhang, Z. Chao, M. Gan, J. Liao, X. Ye, W. You, J. Fu and H. Wen, Chem. Commun., 2022, 58, 1764 DOI: 10.1039/D1CC06255G

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Chemical Communications