Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

Pei Zhao; Jiaxin Huang; Jie Li; Kezhuo Zhang; Wen Yang; Wanxiang Zhao

doi:10.1039/D1CC05964E

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Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes†

Pei Zhao,‡^a Jiaxin Huang,‡^a Jie Li,^a Kezhuo Zhang,^a Wen Yang

*^a and Wanxiang Zhao

*^a

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* Corresponding authors

^a State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P. R. China
E-mail: yangwen@hnu.edu.cn, zhaowanxiang@hnu.edu.cn

Abstract

The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.

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Article information

DOI: https://doi.org/10.1039/D1CC05964E
Article type: Communication
Submitted: 25 Oct 2021
Accepted: 01 Dec 2021
First published: 02 Dec 2021

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Chem. Commun., 2022,58, 302-305

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Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

P. Zhao, J. Huang, J. Li, K. Zhang, W. Yang and W. Zhao, Chem. Commun., 2022, 58, 302 DOI: 10.1039/D1CC05964E

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Chemical Communications

Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes†

Abstract

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Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

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