Issue 7, 2022
From the journal:

Chemical Communications

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors†

Thao M. Xiong,a   Edzna S. Garcia,a   Junfeng Chen,a   Lingyang Zhu, ORCID logo b   Ariale J. Alzonaa  and  Steven C. Zimmerman ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA
E-mail: sczimmer@illinois.edu

b NMR Laboratory, School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana 61801, USA

Abstract

We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst “cofactors” and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.

Graphical abstract: Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CC05578J
Article type
Communication
Submitted
04 Oct 2021
Accepted
15 Dec 2021
First published
15 Dec 2021

Chem. Commun., 2022,58, 985-988

Author version available


Download author version (PDF)

Permissions

Request permissions

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

T. M. Xiong, E. S. Garcia, J. Chen, L. Zhu, A. J. Alzona and S. C. Zimmerman, Chem. Commun., 2022, 58, 985 DOI: 10.1039/D1CC05578J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements