Water-soluble long afterglow carbon dots/silica composites for dual-channel detection of alkaline phosphatase and multi-level information anti-counterfeiting

Abstract

Water-soluble carbon dots/silica (CDs/SiO₂) composites with an ultra-long lifetime of 846.9 ms and an ultra-high afterglow quantum yield of 12.1% were successfully obtained by incorporating CDs into a SiO₂ network. Within the aqueous solution, the SiO₂ layer isolates CDs from the surrounding oxygen. Meanwhile, hydrogen bonds and covalent bonds are formed between the CDs and SiO₂, and these bonds restrict the movement and vibration of the CDs. Accordingly, the non-radiative inactivation rate of the triplet excitons of the CDs is reduced, thereby enhancing the room-temperature phosphorescence of the CDs and triggering thermally activated delayed fluorescence. The multiple properties of the material effectively protect the CDs from the external environment, making CDs/SiO₂ emit a long afterglow in the solid and liquid phases. The prepared CDs/SiO₂ composites have exceptional stability against strong oxidants, acids, bases, and polar solvents. The composites were successfully used in the dual-optical mode detection of alkaline phosphatase, as an anti-counterfeiting ink, and in multi-level information anti-counterfeiting and encryption.