Stress buffering in cyclodextrin-based membranes coated on emulsion droplet surfaces

Abstract

Surface instability of membranes not only plays a critical role in the morphological evolution observed in natural and biological systems, but also underpins a promising way for the bottom-up fabrication of novel functional materials. There is an urgent need for the design of novel building blocks into membranes, and the understanding of the abilities of the membranes to cope with mechanical stress is therefore of considerable importance. Here, we design membranes built with cyclodextrin–oil inclusion complexes, which are formed spontaneously at the oil/water interface by a self-assembly process. We select the oil phases of distinct molecular structures, namely, branched triglyceride oil and straight-chain n-dodecane, and examine the patterns in which the membranes adopt morphological transitions to buffer stress. We discuss two possible buffering scenarios for the behaviors observed in view of structural arrest and interfacial rheology, which are most closely linked to the rigidity of the membranes. The membranes represent fascinating models and shed some light on the origin of arrested stress relaxation.