Recent progress and future challenges in the supramolecular polymerization of metal-containing monomers

Abstract

The self-assembly of discrete molecular entities into functional nanomaterials has become a major research area in the past decades. The library of investigated compounds has diversified significantly, while the field as a whole has matured. The incorporation of metal ions in the molecular design of the (supra-)molecular building blocks greatly expands the potential applications, while also offering a promising approach to control molecular recognition and attractive and/or repulsive intermolecular binding events. Hence, supramolecular polymerization of metal-containing monomers has emerged as a major research focus in the field. In this perspective article, we highlight recent significant advances in supramolecular polymerization of metal-containing monomers and discuss their implications for future research. Additionally, we also outline some major challenges that metallosupramolecular chemists (will) have to face to produce metallosupramolecular polymers (MSPs) with advanced applications and functionalities.

Graphical abstract: Recent progress and future challenges in the supramolecular polymerization of metal-containing monomers

Article information

Article type
Perspective
Submitted
22 Jun 2021
Accepted
04 Sep 2021
First published
08 Sep 2021
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2021, Advance Article

Recent progress and future challenges in the supramolecular polymerization of metal-containing monomers

N. Bäumer, J. Matern and G. Fernández, Chem. Sci., 2021, Advance Article , DOI: 10.1039/D1SC03388C

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