Issue 11, 2021

Ionic liquid-derived polyelectrolyte promoting the biphasic condensation of immiscible reactants at moderate temperature

Abstract

A tri-n-octyl(sulfobutyl)phosphonium-based ionic liquid catalyst (ILC1) formed a triphasic system with glycerol and oleic acid, dissolving both reactants and effectively catalysing their condensation to produce glyceryl oleate. An ILC monomer structurally analogous to ILC1 was co-polymerised with divinylbenzene to afford a cross-linked polyelectrolyte promoting the above reaction at <100 °C.

Graphical abstract: Ionic liquid-derived polyelectrolyte promoting the biphasic condensation of immiscible reactants at moderate temperature

Supplementary files

Article information

Article type
Communication
Submitted
27 Jul 2021
Accepted
23 Aug 2021
First published
27 Aug 2021

React. Chem. Eng., 2021,6, 2014-2017

Ionic liquid-derived polyelectrolyte promoting the biphasic condensation of immiscible reactants at moderate temperature

Y. Kohno and T. Makino, React. Chem. Eng., 2021, 6, 2014 DOI: 10.1039/D1RE00304F

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